Kyle - it is confusing!
Valvo became a subsidiary company of Philips in the '30s and had their factory in Hamburg producing tubes for sale within Germany labelled "Valvo". In addition you also have Philips producing tubes at their many European plants which were then labelled "Valvo" for sale in Germany. So there are German made Valvo ECC82s as well as Dutch made Valvo ECC82s.
So In answer to your question: I haven't heard any German-produced Valvo ECC82s and although they might be excellent tubes in their own right, sonically I don't think they should be considered the same as those I reviewed that came out of the Philips Heerlen plant in Holland in the 1960s, since it is generally said those have a rather unique sound signature.
Therefore I think the crucial part is where they came from rather than what label is on the front. i.e. that they were ECC82s
made in Heerlen, Holland, by Philips in the 1960s, with the grey ladder plates. This can be verified by looking for the Heerlen factory code which is a little right-angled triangle symbol (see pic below, not to be confused with the Copenhagen symbol). As long as it has this factory code symbol then I don't think it matters which brand is on the front. If it was destined to be sold in Germany it would have "Valvo", "Amperex" in the US. Also could just be labelled "Philips" or "Philips Miniwatt", "Hewlett Packard", and many others!
The downside is that since these tubes are pretty old, the codes on the tubes are often in poor shape, almost gone so can be difficult to identify. Generally, the factory codes are what to trust and verify rather than any labels that might say "Made in Holland" on the front, unless the seller really knows their stuff and has a good reputation.
Hopefully you can lay your hands on some of these - they are in the top 3 for me and one of my absolute favourites: creamy and lush with generous liquid bass whilst also retaining a good amount of detail throughout so the sound never seems slack or veiled. Tubey! They are quite popular now but still plenty around I would still expect you to be able to land a pair for well under $100. If you search for "Philips Holland made ECC82s" or "Heerlen ECC82" that should get you started. Let me know how you get on!